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Chemistry of life

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Carbohydrates: polysaccharides

Polysaccharidespolysaccharides
Complex carbohydrates consisting of more than one sugar molecule.
are giant polymers of monosaccharidesmonosaccharides
Single sugars units usually containing 3, 5 or 6 carbon atoms, e.g., glucose.
, all connected by glycosidic linkages. They have an enormous range of functions in different organisms (see above). They may have a relatively simple structure or they may form more complex molecules, depending on the monosaccharide units and the types of glycosidic bondglycosidic bond
The bond formed by a condensation reaction between two a sugar molecule, and another group that might not be a sugar
s involved.

  • Starchthe term starch covers a family of giant molecules all with relatively similar structures. They are all made up of glucoseglucose
    A type of sugar: a mono saccharide with 6 carbon atoms (a hexose sugar).
    units joined by α-glycosidic bonds. The differences between them result from the ratios of α-1,4 and α-1,6 glycosidic bonds in the molecules. Starches are used as storage molecules in plants and are the staple food for most of the human population of the world, found in cereal crops (e.g., wheat, rice), root crops (e.g., sweet potato, cassava) and fruits such as bananas and plantains. Examples of starches include:
Potatoes

1. Amyloseamylose
An unbranched polymer of 200-5000 glucose units all joined by α(1→4) glycosidic bonds. It forms compact spiral molecules so is ideally adapted as a storage molecule.
- an unbranched polymer made in plants made up of 200 - 5000 glucoseglucose
A type of sugar: a mono saccharide with 6 carbon atoms (a hexose sugar).
units all joined by α-1,4 glycosidic bondglycosidic bond
The bond formed by a condensation reaction between two a sugar molecule, and another group that might not be a sugar
s. It forms spiral molecules, so it is very compact – ideal as a storage molecule.

Amylose New

2. Amylopectinamylopectin
A polymer made up of glucose units joined by α(1→4) links with branches at the α(1→6) linkages which form every 25 glucose units, so it is broken down more rapidly than amylose.
- a plant polymer made up of glucoseglucose
A type of sugar: a mono saccharide with 6 carbon atoms (a hexose sugar).
units joined mainly by α-1,4 links but with some α-1,6 linkages, so the chains branch around every 24-30 glucose units. It is not as compact as amyloseamylose
An unbranched polymer of 200-5000 glucose units all joined by α(1→4) glycosidic bonds. It forms compact spiral molecules so is ideally adapted as a storage molecule.
, but as all the chain ends are available for enzymes to hydrolyse the bonds, it can be broken down quickly to provide glucose for cellular respirationcellular respiration
Breaking down glucose (food) without oxygen to provide available energy for the cells. The glucose reacts with oxygen to produce energy in the form of ATP with carbon dioxide and water as waste products.
.

Amylopectin New
  • Glycogena complex carbohydratecarbohydrate
    Energy producing organic compounds which are made of carbon, hydrogen and oxygen. Examples of food containing carbohydrate are rice, pasta, bread and potatoes
     used as an energy store in animal and fungal cells. In humans, glycogen is stored in the liver and the muscles, with very small amounts also stored in the brain. Structurally glycogen is very similar to amylopectinamylopectin
    A polymer made up of glucose units joined by α(1→4) links with branches at the α(1→6) linkages which form every 25 glucose units, so it is broken down more rapidly than amylose.
    but with more α-1,6 linkages – every 8-12 glucoseglucose
    A type of sugar: a mono saccharide with 6 carbon atoms (a hexose sugar).
    units. This means it is very branched and so more compact than amylopectin, and it can be broken down very rapidly to provide the glucose fuel needed for cellular respirationcellular respiration
    Breaking down glucose (food) without oxygen to provide available energy for the cells. The glucose reacts with oxygen to produce energy in the form of ATP with carbon dioxide and water as waste products.
    .
Glycogen New
  • Cellulosecellulose
    A complex carbohydrate which makes up plant cell walls.
    : a complex carbohydratecarbohydrate
    Energy producing organic compounds which are made of carbon, hydrogen and oxygen. Examples of food containing carbohydrate are rice, pasta, bread and potatoes
     made up of β-glucoseglucose
    A type of sugar: a mono saccharide with 6 carbon atoms (a hexose sugar).
    molecules joined by β -1,4 glycosidic linkages. The linking of β glucose units in this way means there are hydroxyl (-OH) groups on both sides of the polymer. Many hydrogen bondhydrogen bond
    An intermolecular attractive force between hydrogen, when it is covalently bonded to a highly electronegative atom (fluorine, oxygen or nitrogen), and an oxygen, nitrogen or fluorine atom on another molecule.
    s form producing strong cross-linking between the long straight cellulose molecules. Cellulose is a very strong material but the molecules do not spiral or branch so they are not compact. Cellulose if the main structural material of plant cell walls. Most animals do not have the enzymes needed to break the β -1,4 glycosidic linkages. Cellulase enzymes are only found in some protista that live in the guts of wood eating termites, and some bacteriabacteria
    Single-celled organism. Has a cell wall, cell membrane, cytoplasm. Its DNA is loosely-coiled in the cytoplasm and there is no distinct nucleus.
    .
Cellulose New

 

The nature of these polysaccharidespolysaccharides
Complex carbohydrates consisting of more than one sugar molecule.
depends on the isomers of glucoseglucose
A type of sugar: a mono saccharide with 6 carbon atoms (a hexose sugar).
involved in the molecules, and the type of glycosidic bondglycosidic bond
The bond formed by a condensation reaction between two a sugar molecule, and another group that might not be a sugar
s formed.

 

Activity

  1. Investigate the main plant sources of carbohydrate foods used around the world.
  2. Produce an infographic to show clearly our relative dependence of different carbohydrate-rich crops

You can find examples of infographics and data visualisation at the links below:
www.informationisbeautiful.net
www.theguardian.com/membership/2014/sep/10/best-infographic-graphic-design